With File Explorer, navigate to the 'C:\ProgramData\The Master Genealogist v9' folder.
Double-click the vcf2.chm file to view the help.
You could make a 'shortcut' on your desktop to this file by right-clicking on the help file and dragging it to your Desktop and selecting 'Create shortcuts here'.
(VCF could no longer be programmed when it became necessary to use a .CHM help file (rather than the .HLP file that VCF uses). I created the vcf2.chm file and Bob included it in the installer so that it would be available outside of VCF.)